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PFSA

Nafion (Perfluorosulfonic Acid)

Glass Transition (Tg)
~110 °C
Melting Point (Tm)
Density
1.98 g/cm³
CAS Number
31175-20-9
Recycling Code
♺ 7
Category
Functional & Smart

Repeat Unit

–[CF₂–CF₂]ₓ–[CF₂–CF(O–C₃F₆–O–C₂F₄–SO₃H)]ᵧ–

The repeating unit is the smallest structural fragment whose repetition builds the whole chain. Subscripts show the relative share of each unit in copolymers.

Key Properties

Phase-separated ionomer: hydrophobic PTFE backbone with hydrophilic sulfonic clusters forming water channels for proton conduction.

Applications

PEM fuel-cell membranes, chlor-alkali cells, electrolysers.

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