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PNIPAM

Poly(N-isopropylacrylamide)

Glass Transition (Tg)
130–140 °C
Melting Point (Tm)
— (amorphous)
Density
~1.1 g/cm³
CAS Number
25189-55-3
Recycling Code
None
Category
Functional & Smart

Repeat Unit

–[CH₂–CH(CONHCH(CH₃)₂)]ₙ–

The repeating unit is the smallest structural fragment whose repetition builds the whole chain. Subscripts show the relative share of each unit in copolymers.

Key Properties

The classic thermoresponsive polymer: sharp LCST at ~32 °C — just below body temperature — causes reversible coil-to-globule collapse and gel deswelling.

Applications

Smart drug release, cell-sheet engineering, sensors, actuators.

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